Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity.
نویسندگان
چکیده
The reproducible formation of a 3D oxalate based coordination compound of formula (NH4)5[Mn(II)2Cr(III)3(ox)9]·10H2O, with an unusual Mn(II)/Cr(III) ratio, is presented. The original topology of the anionic network leads to antiferromagnetic long-range ordering whereas its guests favour high humidity-dependent proton conductivity.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 42 شماره
صفحات -
تاریخ انتشار 2014